Nahcolite | |
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General | |
Category | Carbonate mineral |
Formula (repeating unit) | Sodium bicarbonate (NaHCO3) |
IMA symbol | Nah[1] |
Strunz classification | 5.AA.15 |
Dana classification | 13.01.01.01 |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | P21/n |
Unit cell | a = 7.47, b = 9.68 c = 3.48 [Å]; β = 93.38°; Z = 4 |
Identification | |
Colour | White to colourless, may be grey to brown |
Crystal habit | Elongated crystals, fibrous masses, friable porous aggregates |
Twinning | Common on [101] |
Cleavage | {101} perfect, {111} good, {100} distinct |
Fracture | Conchoidal |
Tenacity | Brittle |
Mohs scale hardness | 2.5 |
Lustre | Vitreous – resinous |
Streak | White |
Diaphaneity | Transparent to translucent |
Specific gravity | 2.21 |
Optical properties | Biaxial (−) |
Refractive index | nα = 1.377 nβ = 1.503 nγ = 1.583 |
Birefringence | δ = 0.206 |
Ultraviolet fluorescence | Short UV=blue-white cream-yellow, Long UV=cream-yellow |
Solubility | Soluble in water |
References | [2][3][4] |
Nahcolite is a soft, colourless or white carbonate mineral with the composition of sodium bicarbonate (NaHCO3) also called thermokalite. It crystallizes in the monoclinic system.[4]
Nahcolite was first described in 1928 for an occurrence in a lava tunnel at Mount Vesuvius, Italy.[2] Its name refers to the elements which compose it: Na, H, C, and O.[5] It occurs as a hot spring and saline lake precipitate or efflorescence; in differentiated alkalic massifs; in fluid inclusions as a daughter mineral phase and in evaporite deposits.[2][4]
It occurs in association with trona, thermonatrite, thenardite, halite, gaylussite, burkeite, northupite and borax.[3] It has been reported in a Roman conduit at Stufe de Nerone, Campi Flegrei, near Naples; in the United States from Searles Lake, San Bernardino County, California; in the Green River Formation, Colorado and Utah; in the Tincalayu deposit, Salar del Hombre Muerto, Salta Province, Argentina; on Mt. Alluaiv, Lovozero Massif and Khibiny Massif, Kola Peninsula, Russia; and around Mount Erebus, Victoria Land, Antarctica.[3]