Neonicotinoid

Neonicotinoids (sometimes shortened to neonics /ˈnnɪks/) are a class of neuro-active insecticides chemically similar to nicotine,[1] developed by scientists at Shell and Bayer in the 1980s.[2]

Neonicotinoids are among the widest-used insecticides in crop protection.[3] They are also widely employed for veterinary purposes including tick and flea control.[3] The first generation of neonicotinoids includes acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, nithiazine, thiacloprid and thiamethoxam. The more recently-marketed generation of neonicotinoids includes cycloxaprid, imidaclothiz, paichongding, sulfoxaflor, guadipyr and flupyradifurone.[4] Imidacloprid has been the most widely used insecticide in the world from 1999[5] through at least 2018.[6][7]

Because they affect the central nervous system of insects, neonicotinoids kill or deleteriously affect a wide variety of both target and non-target insects.[8] They are often applied to seeds before planting as a prophylactic treatment against herbivorous insects. Neonicotinoids are water-soluble, so when the seed sprouts and grows, the developing plant absorbs the pesticide into its tissues as it takes in water.[9] Neonicotinoids can also be applied to the soil directly.[10] Once absorbed, neonicotinoids become present throughout the plant, including in its leaves, flowers, nectar, and pollen.[8]

Neonicotinoid use has been linked to adverse ecological effects, including risks to many non-target organisms, and specifically on bees and pollinators.[9][11][12] A 2018 review by the European Food Safety Authority (EFSA) concluded that most uses of neonicotinoid pesticides represent a risk to wild bees and honeybees.[11][13] In 2022 the United States Environmental Protection Agency (EPA) concluded that neonicotinoids are likely to adversely affect the majority of federally listed endangered or threatened species and of critical habitats.[12] Neonicotinoids widely contaminate wetlands, streams, and rivers, and due to their widespread use, pollinating insects are chronically exposed to them.[14][15] Sublethal effects from chronic low-level exposure to neonicotinoids in the environment are thought to be more common in bees than directly lethal effects. These effects upon bees include difficulty navigating, learning, and foraging, suppressed immune response, lower sperm viability, shortened lifespans of queens, and reduced numbers of new queens produced.[8]

In 2013, the European Union and some neighbouring countries restricted the use of certain neonicotinoids.[16][17][18][19][20][21] In 2018 the EU banned the three main neonicotinoids (clothianidin, imidacloprid and thiamethoxam) for all outdoor uses.[22][23] Several US states have restricted neonicotinoids out of concern for pollinators and bees.[24]

  1. ^ "Neonicotinoid Pesticides & Adverse Health Outcomes". ntp.niehs.nih.gov. National Toxicology Program. Retrieved 20 November 2019.
  2. ^ Kollmeyer WD, Flattum RF, Foster JP, Powell JE, Schroeder ME, Soloway SB (1999). "Discovery of the Nitromethylene Heterocycle Insecticides". In Yamamoto I, Casida J (eds.). Nicotinoid Insecticides and the Nicotinic Acetylcholine Receptor. Tokyo: Springer-Verlag. pp. 71–89. ISBN 978-4-431-70213-9.
  3. ^ a b Jeschke, Peter; Nauen, Ralf; Schindler, Michael; Elbert, Alfred (21 June 2010). "Overview of the Status and Global Strategy for Neonicotinoids". Journal of Agricultural and Food Chemistry. 59 (7). American Chemical Society (ACS): 2897–2908. doi:10.1021/jf101303g. ISSN 0021-8561. PMID 20565065.
  4. ^ Giorio C, Safer A, Sánchez-Bayo F, Tapparo A, Lentola A, Girolami V, et al. (March 2021). "An update of the Worldwide Integrated Assessment (WIA) on systemic insecticides. Part 1: new molecules, metabolism, fate, and transport". Environmental Science and Pollution Research International. 28 (10): 11716–11748. Bibcode:2021ESPR...2811716G. doi:10.1007/s11356-017-0394-3. PMC 7920890. PMID 29105037.
  5. ^ Yamamoto I (1999). "Nicotine to Nicotinoids: 1962 to 1997". In Yamamoto I, Casida J (eds.). Nicotinoid Insecticides and the Nicotinic Acetylcholine Receptor. Tokyo: Springer-Verlag. pp. 3–27. ISBN 978-4-431-70213-9.
  6. ^ Casida JE (January 2018). "Neonicotinoids and Other Insect Nicotinic Receptor Competitive Modulators: Progress and Prospects". Annual Review of Entomology. 63 (1). Annual Reviews: 125–144. doi:10.1146/annurev-ento-020117-043042. PMID 29324040.
  7. ^ Ihara M, Matsuda K (December 2018). "Neonicotinoids: molecular mechanisms of action, insights into resistance and impact on pollinators". Current Opinion in Insect Science. 30. Elsevier: 86–92. Bibcode:2018COIS...30...86I. doi:10.1016/j.cois.2018.09.009. PMID 30553491. S2CID 58767188.
  8. ^ a b c Hladik ML, Main AR, Goulson D (March 2018). "Environmental Risks and Challenges Associated with Neonicotinoid Insecticides". Environmental Science & Technology. 52 (6): 3329–3335. Bibcode:2018EnST...52.3329H. doi:10.1021/acs.est.7b06388. PMID 29481746.
  9. ^ a b Wood TJ, Goulson D (July 2017). "The environmental risks of neonicotinoid pesticides: a review of the evidence post 2013". Environmental Science and Pollution Research International. 24 (21): 17285–17325. Bibcode:2017ESPR...2417285W. doi:10.1007/s11356-017-9240-x. PMC 5533829. PMID 28593544.
  10. ^ "What is a neonicotinoid? - Insects in the City". Texas A&M AgriLife Extension.
  11. ^ a b "Neonicotinoids: risks to bees confirmed | EFSA". www.efsa.europa.eu. 28 February 2018. Retrieved 23 June 2023.
  12. ^ a b US EPA, OCSPP (16 June 2022). "EPA Finalizes Biological Evaluations Assessing Potential Effects of Three Neonicotinoid Pesticides on Endangered Species". www.epa.gov. Retrieved 23 June 2023.
  13. ^ "Conclusion on the peer review of the pesticide risk assessment for bees for the active substance clothianidin". EFSA Journal. 11: 3066. 2013. doi:10.2903/j.efsa.2013.3066.
  14. ^ Stehle S, Ovcharova V, Wolfram J, Bub S, Herrmann LZ, Petschick LL, Schulz R (April 2023). "Neonicotinoid insecticides in global agricultural surface waters - Exposure, risks and regulatory challenges". The Science of the Total Environment. 867: 161383. Bibcode:2023ScTEn.86761383S. doi:10.1016/j.scitotenv.2022.161383. PMID 36621497. S2CID 255534366.
  15. ^ Berens MJ, Capel PD, Arnold WA (April 2021). "Neonicotinoid Insecticides in Surface Water, Groundwater, and Wastewater Across Land-Use Gradients and Potential Effects". Environmental Toxicology and Chemistry. 40 (4): 1017–1033. Bibcode:2021EnvTC..40.1017B. doi:10.1002/etc.4959. PMC 8049005. PMID 33301182.
  16. ^ Cressey D (April 2013). "Europe debates risk to bees". Nature. 496 (7446): 408. Bibcode:2013Natur.496..408C. doi:10.1038/496408a. PMID 23619669.
    Gill RJ, Ramos-Rodriguez O, Raine NE (November 2012). "Combined pesticide exposure severely affects individual- and colony-level traits in bees". Nature. 491 (7422): 105–108. Bibcode:2012Natur.491..105G. doi:10.1038/nature11585. PMC 3495159. PMID 23086150.
  17. ^ Dicks L (February 2013). "Bees, lies and evidence-based policy". Nature. 494 (7437): 283. Bibcode:2013Natur.494..283D. doi:10.1038/494283a. PMID 23426287.
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  18. ^ Osborne JL (November 2012). "Ecology: Bumblebees and pesticides". Nature. 491 (7422): 43–45. Bibcode:2012Natur.491...43O. doi:10.1038/nature11637. PMID 23086148. S2CID 532877.
  19. ^ Cressey D (2013). "Reports spark row over bee-bothering insecticides". Nature. doi:10.1038/nature.2013.12234. S2CID 88428354.
  20. ^ "Bees & Pesticides: Commission goes ahead with plan to better protect bees". European Commission. 30 May 2013. Archived from the original on 6 November 2013.
  21. ^ McDonald-Gibson C (29 April 2013). "'Victory for bees' as European Union bans neonicotinoid pesticides blamed for destroying bee population". The Independent. Archived from the original on 1 May 2013. Retrieved 1 May 2013.
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  23. ^ "EU nations back ban on insecticides to protect honey bees". Reuters. 27 April 2018. Archived from the original on 27 April 2018. Retrieved 27 April 2018.
  24. ^ "Minnesota Cracks Down On Neonic Pesticides, Promising Aid To Bees". NPR.org. Retrieved 3 May 2018.