Neptunium(VI) fluoride

Neptunium(VI) fluoride[1]
Stereo structural formula of Neptunium hexafluoride
Names
IUPAC name
Neptunium(VI) fluoride
Other names
Neptunium hexafluoride
Identifiers
3D model (JSmol)
  • InChI=1S/6FH.Np/h6*1H;/q;;;;;;+6/p-6 ☒N
  • F[Np](F)(F)(F)(F)F
Properties
F6Np
Molar mass 351 g·mol−1
Appearance orange crystals
Melting point 54.4 °C (129.9 °F; 327.5 K)
Boiling point 55.18 °C (131.32 °F; 328.33 K)
Structure
Orthorhombic, oP28
Pnma, No. 62
octahedral (Oh)
0 D
Thermochemistry[2]: 736 
229.1 ± 0.5 J·K−1·mol−1
Related compounds
Related fluoroNeptuniums
Neptunium trifluoride

Neptunium tetrafluoride

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N (what is checkY☒N ?)

Neptunium(VI) fluoride (NpF6) is the highest fluoride of neptunium, it is also one of seventeen known binary hexafluorides. It is a volatile orange crystalline solid.[1] It is relatively hard to handle, being very corrosive, volatile and radioactive. Neptunium hexafluoride is stable in dry air but reacts vigorously with water.

At normal pressure, it melts at 54.4 °C and boils at 55.18 °C. It is the only neptunium compound that boils at a low temperature. Due to these properties, it is possible to easily separate neptunium from spent fuel.

  1. ^ a b Gmelins Handbuch der anorganischen Chemie, System Nr. 71, Transurane, Teil C, p. 108–114.
  2. ^ Yoshida, Zenko; Johnson, Stephen G.; Kimura, Takaumi; Krsul, John R. Neptunium.