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Names | |
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IUPAC name
Neptunium(VI) fluoride
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Other names
Neptunium hexafluoride
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Identifiers | |
3D model (JSmol)
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PubChem CID
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Properties | |
F6Np | |
Molar mass | 351 g·mol−1 |
Appearance | orange crystals |
Melting point | 54.4 °C (129.9 °F; 327.5 K) |
Boiling point | 55.18 °C (131.32 °F; 328.33 K) |
Structure | |
Orthorhombic, oP28 | |
Pnma, No. 62 | |
octahedral (Oh) | |
0 D | |
Thermochemistry[2]: 736 | |
Std molar
entropy (S⦵298) |
229.1 ± 0.5 J·K−1·mol−1 |
Related compounds | |
Related fluoroNeptuniums
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Neptunium trifluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Neptunium(VI) fluoride (NpF6) is the highest fluoride of neptunium, it is also one of seventeen known binary hexafluorides. It is a volatile orange crystalline solid.[1] It is relatively hard to handle, being very corrosive, volatile and radioactive. Neptunium hexafluoride is stable in dry air but reacts vigorously with water.
At normal pressure, it melts at 54.4 °C and boils at 55.18 °C. It is the only neptunium compound that boils at a low temperature. Due to these properties, it is possible to easily separate neptunium from spent fuel.