Nitrocellulose

Nitrocellulose[1]
Cosmetic pads made of nitrocellulose
Names
Other names
Cellulose nitrate; Flash paper; Flash cotton; Flash string; Gun cotton; Collodion; Pyroxylin
Identifiers
ChemSpider
  • none
UNII
Properties
(C
6
H
9
(NO
2
)O
5
)
n
(mononitrocellulose)

(C
6
H
8
(NO
2
)
2
O
5
)
n
(dinitrocellulose)
(C
6
H
7
(NO
2
)
3
O
5
)
n
(trinitrocellulose, pictured in structures above)

Appearance Yellowish white cotton-like filaments
Melting point 160 to 170 °C (320 to 338 °F; 433 to 443 K) (ignites)
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 3: Liquids and solids that can be ignited under almost all ambient temperature conditions. Flash point between 23 and 38 °C (73 and 100 °F). E.g. gasolineInstability 3: Capable of detonation or explosive decomposition but requires a strong initiating source, must be heated under confinement before initiation, reacts explosively with water, or will detonate if severely shocked. E.g. hydrogen peroxideSpecial hazards (white): no code
2
3
3
Flash point 4.4 °C (39.9 °F; 277.5 K)
Lethal dose or concentration (LD, LC):
10 mg/kg (mouse, IV)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Nitrocellulose (also known as cellulose nitrate, flash paper, flash cotton, guncotton, pyroxylin and flash string, depending on form) is a highly flammable compound formed by nitrating cellulose through exposure to a mixture of nitric acid and sulfuric acid. One of its first major uses was as guncotton, a replacement for gunpowder as propellant in firearms. It was also used to replace gunpowder as a low-order explosive in mining and other applications. In the form of collodion it was also a critical component in an early photographic emulsion, the use of which revolutionized photography in the 1860s. In the 20th century it was adapted to automobile lacquer and adhesives.

  1. ^ Merck Index (11th ed.). p. 8022.