Organonickel chemistry

organonickel
organonickel

Organonickel chemistry is a branch of organometallic chemistry that deals with organic compounds featuring nickel-carbon bonds.[1][2] They are used as a catalyst, as a building block in organic chemistry and in chemical vapor deposition. Organonickel compounds are also short-lived intermediates in organic reactions. The first organonickel compound was nickel tetracarbonyl Ni(CO)4, reported in 1890 and quickly applied in the Mond process for nickel purification. Organonickel complexes are prominent in numerous industrial processes including carbonylations, hydrocyanation, and the Shell higher olefin process.[3][4]

  1. ^ F.A. Carey R.J. Sundberg Advanced Organic Chemistry 2nd Ed. ISBN 0-306-41199-7
  2. ^ Comprehensive organometallic chemistry III Robert Crabtree, Mike Mingos 2006 ISBN 0-08-044590-X
  3. ^ Ananikov, Valentine P. (2015). "Nickel: The "Spirited Horse" of Transition Metal Catalysis". ACS Catalysis. 5 (3): 1964–1971. doi:10.1021/acscatal.5b00072.
  4. ^ Tasker, Sarah Z.; Standley, Eric A.; Jamison, Timothy F. (2014). "Recent Advances in Homogeneous Nickel Catalysis". Nature. 509 (7500): 299–309. Bibcode:2014Natur.509..299T. doi:10.1038/nature13274. PMC 4344729. PMID 24828188.