Palladium(II) acetate

Palladium(II) acetate
Names
IUPAC name
Palladium(II) acetate
Other names
Palladium diacetate
hexakis(acetato)tripalladium
bis(acetato)palladium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.020.151 Edit this at Wikidata
EC Number
  • 222-164-4
RTECS number
  • AJ1900000
UNII
  • InChI=1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2 checkY
    Key: YJVFFLUZDVXJQI-UHFFFAOYSA-L checkY
  • InChI=1/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
    Key: YJVFFLUZDVXJQI-NUQVWONBAH
  • ionic form: [Pd+2].[O-]C(=O)C.[O-]C(=O)C
  • coordination form (cyclic trimer): O0[C-](C)O[Pd+2]3(O[C-](C)O1)O[C-](C)O[Pd+2]1(O[C-](C)O2)O[C-](C)O[Pd-2]02O[C-](C)O3
Properties
Pd(CH3COO)2
Molar mass 224.51 g/mol
Appearance Brown yellow solid
Density 2.19 g/cm3
Melting point 205 °C (401 °F; 478 K) decomposes
low
Structure
monoclinic
square planar
0 D
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
considered nonhazardous
GHS labelling:[1]
GHS05: CorrosiveGHS07: Exclamation markGHS09: Environmental hazard
Danger
H317, H318, H410
P261, P272, P273, P280, P302+P352, P305+P351+P338
Safety data sheet (SDS) [1]
Related compounds
Other anions
Palladium(II) chloride
Other cations
Platinum(II) acetate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Palladium(II) acetate is a chemical compound of palladium described by the formula [Pd(O2CCH3)2]n, abbreviated [Pd(OAc)2]n. It is more reactive than the analogous platinum compound. Depending on the value of n, the compound is soluble in many organic solvents and is commonly used as a catalyst for organic reactions.[2]

  1. ^ "520764 [Pd(OAc)2]3". Sigma-Aldrich. Retrieved 23 December 2021.
  2. ^ Grennberg, Helena; Foot, Jonathan S.; Banwell, Martin G.; Roman, Daniela Sustac (2001). "Palladium(II) Acetate". Encyclopedia of Reagents for Organic Synthesis. pp. 1–35. doi:10.1002/047084289X.rp001.pub3. ISBN 978-0-470-84289-8.