Palygorskite

Palygorskite
A sample of palygorskite from Hnúšťa, Slovakia.
General
CategoryPhyllosilicate[1][2]
Formula
(repeating unit)
(Mg,Al)2Si4O10(OH)·4(H2O) Al2Mg2◻2Si8O20(OH)2(H2O)4 · 4H2O[3]
IMA symbolPlg[4]
Strunz classification9.EE.20[3]
Crystal systemMonoclinic,[3] orthorhombic[5]
Crystal classPrismatic (2/m)[3]
(same H-M symbol)
Space groupB2/m and setting C2/m, [3] P 21 21 21[6]
Unit cella = 12.78 Å, b = 17.86 Å,
c = 5.24 Å; β = 95.78°; Z = 4[3]
Identification
ColorWhite, grayish, yellowish, gray-green[3]
Crystal habitCommonly fibrous, tangled mats known as mountain leather. Individual, small crystals are lath-shaped[3]
CleavageDistinct/good, good on {110}[3]
TenacityTough[3]
Mohs scale hardness2 – 2.5[3]
LusterWaxy, earthy[3]
DiaphaneityTranslucent[3]
Specific gravity1 – 2.6[3]
Density2.1 - 2.6 g/cm3 (Measured); 2.35 g/cm3 (Calculated)[3]
Optical propertiesBiaxial (−)[3]
Refractive indexnα = 1.522 – 1.528 nβ = 1.530 – 1.546 nγ = 1.533 – 1.548[3]
Birefringenceδ = 0.011 – 0.020[3]
PleochroismX= pale yellow Y=Z= pale yellow-green[3]
Common impuritiesFe,K [3]
References[1][2][3][7]

Palygorskite (Russian: Палыгорскит) or attapulgite is a magnesium aluminium phyllosilicate with the chemical formula (Mg,Al)2Si4O10(OH)·4(H2O) that occurs in a type of clay soil common to the Southeastern United States. It is one of the types of fuller's earth. Some smaller deposits of this mineral can be found in Mexico, where its use is tied to the manufacture of Maya blue in pre-Columbian times.[2][3][8]

  1. ^ a b "Palygorskite Mineral Data". Webmineral.com. David Barthelmy. 2024. Archived from the original on 2024-04-20. Retrieved 29 August 2024.
  2. ^ a b c Lu, Yushen; Wang, Aiqin (2022). "From structure evolution of palygorskite to functional material: A review". Microporous and Mesoporous Materials. 333: 111765. Bibcode:2022MicMM.33311765L. doi:10.1016/j.micromeso.2022.111765. Retrieved 20 September 2009.
  3. ^ a b c d e f g h i j k l m n o p q r s t u v "Palygorskite. A valid IMA mineral species - grandfathered". Mindat.org. Hudson Institute of Mineralogy. 2024. Retrieved 29 August 2024.
  4. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  5. ^ Garcia-Rivas, Javier; Sánchez del Río, Manuel; García-Romero, Emilia; Suárez, Mercedes 2017
  6. ^ Wiersma 1970, p. 87.
  7. ^ "Palygorskite (Mg,Al)2 Si4 O10 (OH).4H2O" (PDF). handbookofmineralogy.com. Mineral Data Publishing, version 1.2. 2001. Archived from the original (PDF) on 2022-05-01. Retrieved 29 August 2024. Palygorskite in the Handbook of Mineralogy.
  8. ^ Arnold 2005