Pentlandite

Pentlandite
Pentlandite, Pyrrhotite-540342
3.1 × 2.6 cm mass of pentlandite with some pyrrhotite
General
CategorySulfide mineral
Formula
(repeating unit)
iron nickel sulfide: (Fe,Ni)9S8
IMA symbolPn[1]
Strunz classification2.BB.15a
Dana classification2.7.1.1
Crystal systemIsometric
Crystal classHexoctahedral (m3m)
H-M symbol: (4/m 3 2/m)
Space groupFm3m
Unit cella = 9.928 Å, Z = 4
Identification
Formula mass771.94 g/mol
ColorYellowish bronze
Crystal habitHexoctahedral rare; massive to granular
CleavageAbsent – octahedral parting on {111}
FractureConchoidal
TenacityBrittle
Mohs scale hardness3.5–4
LusterMetallic
StreakLight bronze-brown[2][3][4][5]
Greenish black[6][7][8]
DiaphaneityOpaque
Specific gravity4.6–5.0
Density4.6–5 g/cm3
Fusibility1.5–2
Other characteristicsBecomes magnetic upon heating
References[9][2][3][4][5][6][7][8]
Pentlandite in pyrrhotite, ore specimen from the Sudbury Basin (field of view 3.4 cm)

Pentlandite is an ironnickel sulfide with the chemical formula (Fe,Ni)9S8. Pentlandite has a narrow variation range in nickel to iron ratios (Ni:Fe), but it is usually described as 1:1. In some cases, this ratio is skewed by the presence of pyrrhotite inclusions. It also contains minor cobalt, usually at low levels as a fraction of weight.

Pentlandite forms isometric crystals, but it is normally found in massive granular aggregates. It is brittle with a hardness of 3.5–4 and specific gravity of 4.6–5.0 and is non-magnetic. It has a yellowish bronze color and a metallic luster.[10]

Pentlandite is found in abundance within ultramafic rocks, making it one of the most important sources of mined nickel.[11] It also occasionally occurs within mantle xenoliths and "black smoker" hydrothermal vents.[12]

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b Handbook of Mineralogy
  3. ^ a b Mindat.org
  4. ^ a b Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., Wiley, p. 280-281 ISBN 0-471-80580-7
  5. ^ a b Mindat.org - Forum
  6. ^ a b Webmineral.com
  7. ^ a b "Pentlandit" (in German).
  8. ^ a b Schumann, Walter (1991). Mineralien aus aller Welt (in German) (2nd ed.). BLV. p. 224. ISBN 978-3-405-14003-8.
  9. ^ Mineralienatlas
  10. ^ "Pentlandite". www.mindat.org. Retrieved 2023-02-20.
  11. ^ Kerfoot, Derek G. E. (2005). "Nickel". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a17_157. ISBN 978-3527306732.
  12. ^ "Pentlandite" (PDF). Handbook of Mineralogy.