Phosphorus sesquisulfide

Phosphorus sesquisulfide

Names
IUPAC names Tetraphosphorus trisulfide or 3,5,7-trithia-1,2,4,6-tetraphosphatricyclo[2.2.1.02,6]heptane
Other names phosphorus trisulfide, phosphorus sesquisulfide, phosphorus sulfide
Identifiers
CAS Number	1314-85-8 Y
3D model (JSmol)	Interactive image
ChemSpider	14134 Y
ECHA InfoCard	100.013.860
PubChem CID	14818
RTECS number	TH4330000
UNII	8V5Q0M194Y Y
CompTox Dashboard (EPA)	DTXSID4074562
InChI InChI=1S/P4S3/c5-1-2-3(1)7-4(5)6-2 Y Key: RWQFRHVDPXXRQN-UHFFFAOYSA-N Y InChI=1/P4S3/c5-1-2-3(1)7-4(5)6-2 Key: RWQFRHVDPXXRQN-UHFFFAOYAM
SMILES S1P2P3SP1SP23
Properties
Chemical formula	P4S3
Molar mass	220.093 g/mol
Appearance	Yellow, yellow-green or gray solid
Density	2.08 g.cm3,[1] solid
Melting point	172.5 °C (342.5 °F; 445.6 K)
Boiling point	408 °C (766 °F; 681 K)
Structure
Crystal structure	orthorhombic, Schönflies notation D2h
Space group	Pmnb
Point group	C3v
Related compounds
Related compounds	P4S10 P4O6
Hazards
Occupational safety and health (OHS/OSH):
Main hazards	Irritant
GHS labelling:
Pictograms
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is YN ?) Infobox references

Phosphorus sesquisulfide is the inorganic compound with the formula P₄S₃. It was developed by Henri Sevene and Emile David Cahen in 1898 as part of their invention of friction matches that did not pose the health hazards of white phosphorus.^[2][3] This yellow solid is one of two commercially produced phosphorus sulfides. It is a component of "strike anywhere" matches.

Depending on purity, samples can appear yellow-green to grey. The compound was discovered by G. Lemoine and first produced safely in commercial quantities in 1898 by Albright and Wilson. It dissolves in an equal weight of carbon disulfide (CS₂), and in a 1:50 weight ratio of benzene. Unlike some other phosphorus sulfides, P₄S₃ is slow to hydrolyze and has a well-defined melting point.