Phosphoryl chloride difluoride

Phosphoryl chloride difluoride
Names
Other names
Chlorodifluorophosphorus oxide, difluorophosphoryl chloride, phosphoryl chloride
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/ClF2OP/c1-5(2,3)4
    Key: BJHSNICXDHWUGU-UHFFFAOYSA-N
  • O=P(F)(F)Cl
Properties
ClF2OP
Molar mass 120.42 g·mol−1
Density 1.6555 g/mL (liquid); 4.922 g/L (gas)[1]
Melting point −96.4 °C (−141.5 °F; 176.8 K)
Boiling point 3.1 °C (37.6 °F; 276.2 K)
Structure[2] at 120 K
Orthorhombic
Pnma
a = 13.243, b = 5.595, c = 9.918
734.9
8
tetrahedral
Related compounds
Related phosphoryl halides
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Phosphoric chloride difluoride POF2Cl is a colourless gas. At one atmosphere pressure the gas condenses to a liquid at 3.1 °C and freezes at −96.4.[3] Alternate names are difluorophosphoryl chloride[3] or phosphoryl chloride difluoride.

  1. ^ Handbook of Chemistry and Physics (87 ed.). pp. 4–81.
  2. ^ Cite error: The named reference rov was invoked but never defined (see the help page).
  3. ^ a b GEORGE B. KAUFFMAN; RUSSELL FULLER; JAMES FELSER; CHARLES M. FLYNN, JR.; MICHAEL T. POPE (1974). PARSHALL, GEORGE W. (ed.). Phosphoric Chloride Difluoride. Inorganic Syntheses. Vol. 15. pp. 195–196. ISBN 0070485216.