Photoredox catalysis

Photoredox catalysis is a branch of photochemistry that uses single-electron transfer. Photoredox catalysts are generally drawn from three classes of materials: transition-metal complexes, organic dyes, and semiconductors. While organic photoredox catalysts were dominant throughout the 1990s and early 2000s,[1] soluble transition-metal complexes are more commonly used today.

Schematic diagram of [Ru(bipy)3]2+, a typical photoredox catalyst.
  1. ^ Romero, Nathan A.; Nicewicz, David A. (10 June 2016). "Organic Photoredox Catalysis". Chemical Reviews. 2016 (116): 10075–10166. doi:10.1021/acs.chemrev.6b00057. PMID 27285582.