Poly(dichlorophosphazene)

Poly(dichlorophosphazene)
Names
Other names
Dichlorophosphazine polymer; Phosphonitrilechloride polymer
Identifiers
Abbreviations PDCP
ChemSpider
  • none
ECHA InfoCard 100.152.298 Edit this at Wikidata
Properties
(PNCl2)n
Density 1.823 g/mL[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Poly(dichlorophosphazene), also called dichlorophosphazine polymer or phosphonitrilechloride polymer, is a chemical compound with formula (PNCl2)n. It is an inorganic (hence carbon-free) chloropolymer, whose backbone is a chain of alternating phosphorus and nitrogen atoms, connected by alternating single and double covalent bonds.

The compound can be prepared by polymerization of hexachlorophosphazene ((PNCl2)3) by heating to ca. 250 °C.[2][3] It is an "inorganic rubber" and the starting material for many other polymers with the -P=N- backbone (polyphosphazenes), which have important commercial uses.

  1. ^ "Poly(dichlorophosphazene)". Sigma-Aldrich.
  2. ^ Hans Rytger Kricheldorf (1991), Handbook of Polymer Synthesis
  3. ^ Mario Gleria, Roger De Jaeger (2004) Phosphazenes: A Worldwide InsightNova Publishers, 2004. 1047 pages. ISBN 1-59033-423-X, 9781590334232