In mathematics and physics, a quantum graph is a linear, network-shaped structure of vertices connected on edges (i.e., a graph) in which each edge is given a length and where a differential (or pseudo-differential) equation is posed on each edge. An example would be a power network consisting of power lines (edges) connected at transformer stations (vertices); the differential equations would then describe the voltage along each of the lines, with boundary conditions for each edge provided at the adjacent vertices ensuring that the current added over all edges adds to zero at each vertex.
Quantum graphs were first studied by Linus Pauling as models of free electrons in organic molecules in the 1930s. They also arise in a variety of mathematical contexts,[1] e.g. as model systems in quantum chaos, in the study of waveguides, in photonic crystals and in Anderson localization, or as limit on shrinking thin wires. Quantum graphs have become prominent models in mesoscopic physics used to obtain a theoretical understanding of nanotechnology. Another, more simple notion of quantum graphs was introduced by Freedman et al.[2]
Aside from actually solving the differential equations posed on a quantum graph for purposes of concrete applications, typical questions that arise are those of controllability (what inputs have to be provided to bring the system into a desired state, for example providing sufficient power to all houses on a power network) and identifiability (how and where one has to measure something to obtain a complete picture of the state of the system, for example measuring the pressure of a water pipe network to determine whether or not there is a leaking pipe).