Quinone

The quinones are a class of organic compounds that are formally "derived from aromatic compounds [such as benzene or naphthalene] by conversion of an even number of –CH= groups into –C(=O)– groups with any necessary rearrangement of double bonds", resulting in "a fully conjugated cyclic dione structure".[1][2][3] The archetypical member of the class is 1,4-benzoquinone or cyclohexadienedione, often called simply "quinone" (thus the name of the class). Other important examples are 1,2-benzoquinone (ortho-quinone), 1,4-naphthoquinone and 9,10-anthraquinone.

The name is derived from that of quinic acid (with the suffix "-one" indicating a ketone), since it is one of the compounds obtained upon oxidation of quinic acid.[4] Quinic acid, like quinine is obtained from cinchona bark, called quinaquina in the indigenous languages of Peruvian tribes.

  1. ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "Quinones". doi:10.1351/goldbook.Q05015
  2. ^ Patai, Saul; Rappoport, Zvi, eds. (1988). The Quinonoid Compounds: Vol. 1 (1988). doi:10.1002/9780470772119. ISBN 9780470772119.
  3. ^ Patai, Saul; Rappoport, Zvi, eds. (1988). The Quinonoid Compounds: Vol. 2 (1988). doi:10.1002/9780470772126. ISBN 9780470772126.
  4. ^ The Chemical News and Journal of Physical Science. Griffin, Bohn and Company. 1773.