Reductive elimination

Reductive elimination is an elementary step in organometallic chemistry in which the oxidation state of the metal center decreases while forming a new covalent bond between two ligands. It is the microscopic reverse of oxidative addition, and is often the product-forming step in many catalytic processes. Since oxidative addition and reductive elimination are reverse reactions, the same mechanisms apply for both processes, and the product equilibrium depends on the thermodynamics of both directions.[1][2]

  1. ^ Crabtree, Robert H. (2014). The Organometallic Chemistry of the Transition Metals (6 ed.). Wiley. p. 173. ISBN 978-1-118-13807-6.
  2. ^ Hartwig, John F. (2010). Organotransition Metal Chemistry, from Bonding to Catalysis. University Science Books. p. 321. ISBN 978-1-891389-53-5.