| Seesaw molecular geometry | |
|---|---|
 | |
| Examples | SF4 |
| Point group | C2v |
| Coordination number | 4 |
| Bond angle(s) | Ideal ax-ax 180°, eq-eq 120°, ax-eq 90° SF4 ax-ax 173.1°, eq-eq 101.6° |
| μ (Polarity) | >0 |
Disphenoidal or seesaw (also known as sawhorse[1]) is a type of molecular geometry where there are four bonds to a central atom with overall C2v molecular symmetry. The name "seesaw" comes from the observation that it looks like a playground seesaw. Most commonly, four bonds to a central atom result in tetrahedral or, less commonly, square planar geometry.
The seesaw geometry occurs when a molecule has a steric number of 5, with the central atom being bonded to 4 other atoms and 1 lone pair (AX4E1 in AXE notation). An atom bonded to 5 other atoms (and no lone pairs) forms a trigonal bipyramid with two axial and three equatorial positions, but in the seesaw geometry one of the atoms is replaced by a lone pair of electrons, which is always in an equatorial position. This is true because the lone pair occupies more space near the central atom (A) than does a bonding pair of electrons. An equatorial lone pair is repelled by only two bonding pairs at 90°, whereas a hypothetical axial lone pair would be repelled by three bonding pairs at 90° which would make the molecule unstable. Repulsion by bonding pairs at 120° is much smaller and less important.[2][1]
- ^ a b Shields, Shawn P. "The Trigonal Bipyramid Geometry (SN = 5) (VSEPR Part 4)" (PDF). Chemistry. Retrieved 3 April 2022.
SN = 5 with One Lone Pair. Molecular Shape: Sawhorse or Seesaw
- ^ Miessler, Gary L.; Tarr, Donald A. (1999). Inorganic Chemistry (2nd ed.). Prentice-Hall. pp. 58–59. ISBN 0-13-841891-8.