Sodium chlorite

Sodium chlorite
The sodium cation
The sodium cation
Space-filling model of the chlorite anion
Space-filling model of the chlorite anion
Names
IUPAC name
Sodium chlorite
Other names
Chlorous acid, sodium salt
Textone
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.028.942 Edit this at Wikidata
EC Number
  • 231-836-6
KEGG
RTECS number
  • VZ4800000
UNII
UN number 1496
  • InChI=1S/ClHO2.Na/c2-1-3;/h(H,2,3);/q;+1/p-1 checkY
    Key: UKLNMMHNWFDKNT-UHFFFAOYSA-M checkY
  • InChI=1/ClHO2.Na/c2-1-3;/h(H,2,3);/q;+1/p-1
    Key: UKLNMMHNWFDKNT-REWHXWOFAT
  • [Na+].[O-]Cl=O
Properties
NaClO2
Molar mass 90.442 g/mol (anhydrous)
144.487 g/mol (trihydrate)
Appearance white solid
Odor odorless
Density 2.468 g/cm3, solid
Melting point anhydrous decomposes at 180–200 °C
trihydrate decomposes at 38 °C
75.8 g/100 mL (25 °C)
122 g/100 mL (60 °C)
Solubility slightly soluble in methanol, ethanol
Acidity (pKa) 10-11
Structure
monoclinic
Thermochemistry
-307.0 kJ/mol
Pharmacology
D03AX11 (WHO)
Hazards
Occupational safety and health (OHS/OSH):
Ingestion hazards
Category 3
Inhalation hazards
Category 2
Eye hazards
Category 1
Skin hazards
Category 1B
GHS labelling:
GHS03: Oxidizing GHS05: Corrosive GHS06: Toxic GHS09: Environmental hazard
Danger
H272, H301, H310, H314, H330, H400
P210, P220, P221, P260, P262, P264, P270, P271, P273, P280, P284, P301+P330+P331, P303+P361+P353, P305+P351+P338, P310, P361, P363, P370+P378, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
350 mg/kg (rat, oral)
Safety data sheet (SDS) SDS
Related compounds
Other anions
Sodium chloride
Sodium hypochlorite
Sodium chlorate
Sodium perchlorate
Other cations
Potassium chlorite
Barium chlorite
Related compounds
Chlorine dioxide
Chlorous acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Sodium chlorite (NaClO2) is a chemical compound used in the manufacturing of paper and as a disinfectant.