Sodium cyanoborohydride

Sodium cyanoborohydride
Line-bond structure of sodium cyanoborohydride
Names
IUPAC name
Sodium cyanoboranuide
Other names
Sodium cyanotrihydridoborate
Identifiers
3D model (JSmol)
ECHA InfoCard 100.043.001 Edit this at Wikidata
EC Number
  • 247-317-2
UNII
  • InChI=1S/CH3BN.Na/c2-1-3;/h2H3;/q-1;+1
  • [BH3-]C#N.[Na+]
Properties
Na[BH3(CN)]
Molar mass 62.84 g·mol−1
Appearance white powder, hygroscopic
Density 1.083 g/cm (25°C)3
Melting point 242 °C (468 °F; 515 K) decomposes
212 g/(100 mL) (29 °C)
Solubility soluble in water, ethanol, diglyme, tetrahydrofuran, methanol
slightly soluble in methanol
insoluble in diethyl ether
Structure
4 at boron atom
Tetrahedral at boron atom
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
 Flammable solid, fatal if swallowed, in contact with skin or if inhaled
Contact with acids liberates very toxic gas
Contact with water liberates highly flammable gas
GHS labelling:
GHS02: FlammableGHS05: CorrosiveGHS06: Toxic
Danger
H228, H300, H310, H314, H330, H410
P210, P260, P264, P273, P280, P284
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 4: Very short exposure could cause death or major residual injury. E.g. VX gasFlammability 3: Liquids and solids that can be ignited under almost all ambient temperature conditions. Flash point between 23 and 38 °C (73 and 100 °F). E.g. gasolineInstability 2: Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water. E.g. white phosphorusSpecial hazards (white): no code
4
3
2
5 mg/m3 (TWA)
Safety data sheet (SDS) Sigma Aldrich[1]
Related compounds
Other anions
 Sodium borohydride
Related compounds
 Lithium aluminium hydride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Sodium cyanoborohydride is a chemical compound with the formula Na[BH3(CN)]. It is a colourless salt used in organic synthesis for chemical reduction including that of imines and carbonyls. Sodium cyanoborohydride is a milder reductant than other conventional reducing agents.[2]

  1. ^ Sigma-Aldrich Co., Sodium cyanoborohydride. Retrieved on 2014-11-09.
  2. ^ Baxter, Ellen W.; Reitz, Allen B. (9 January 2002). "Reductive Aminations of Carbonyl Compounds with Borohydride and Borane Reducing Agents". Organic Reactions: 1–714. doi:10.1002/0471264180.or059.01. ISBN 0-471-26418-0.