Stilbite

Stilbite
General
CategoryTectosilicate, Zeolite
Formula
(repeating unit)
Stilbite-Ca: NaCa4(Si27Al9)O72·28(H2O)
Stilbite-Na: Na9(Si27Al9)O72·28(H2O)
IMA symbolStb[1]
Strunz classification9.GE.10 (10 ed)
8/J.23-30 (8 ed)
Dana classification77.1.4.3
Crystal systemMonoclinic,
also triclinic and orthorhombic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupC2/m (monoclinic)
Amma (orthorhombic)
Identification
Formula massStilbite-Ca: 2,840 g/mol
Stilbite-Na: 2,864 g/mol
ColorUsually colorless, white or pink
Crystal habitThin tabular, aggregates sheaf-like or in bow-ties, also fibrous and globular.
TwinningVery common on {001}
CleavagePerfect on {010}
FractureConchoidal or uneven
TenacityBrittle
Mohs scale hardness3+12 to 4
LusterVitreous, pearly on {010}
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity2.12 to 2.22
Optical propertiesBiaxial (−)
Refractive indexNx = 1.479 to 1.492, Ny = 1.485 to 1.500, Nz = 1.489 to 1.505[2][3] Nx = 1.484 to 1.500, Ny = 1.492 to 1.507, Nz = 1.494 to 1.513[4][5]
FusibilityEasily fused by blowpipe (~1050 °C) to produce a white "enamel"[6]
SolubilityDecomposes in HCl[6]
References[3][4]

[5][7]

[8][9] [10][11]

Stilbite is the name of a series of tectosilicate minerals of the zeolite group. Prior to 1997, stilbite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named:

  • Stilbite-Ca
  • Stilbite-Na

Stilbite-Ca, by far the more common of the two, is a hydrous calcium sodium and aluminium silicate, NaCa4(Si27Al9)O72·28(H2O). In the case of stilbite-Na, sodium dominates over calcium. The species are visually indistinguishable, and the series name stilbite is still used whenever testing has not been performed.

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Rudy W. Tschernich (1992) Zeolites of the World. Geoscience Press
  3. ^ a b "Stilbite-Ca Mineral Data".
  4. ^ a b http://www.mindat.org/min-7313.html stilbite-Ca
  5. ^ a b "Archived copy" (PDF). Archived from the original (PDF) on 2020-03-29. Retrieved 2010-07-29.{{cite web}}: CS1 maint: archived copy as title (link)
  6. ^ a b Klein, Cornelis and Cornelius S. Hurlbut, 1985, Manual of Mineralogy, Wiley, pp. 465–466 ISBN 0-471-80580-7
  7. ^ Gaines et al (1997) Dana’s New Mineralogy Eighth Edition. Wiley
  8. ^ http://www.mindat.org/min-7314.html stilbite-Na
  9. ^ "Stilbite-Na Mineral Data".
  10. ^ Slaughter, M. (1970). "Crystal structure of stilbite". American Mineralogist. 55: 387–397. Retrieved 30 December 2020.
  11. ^ Cruciani, Giuseppe; Artioli, Gilberto; Gualtieri, Alessandro; Stahl, Kenny; Hanson, Jonathan C. (1 August 1997). "Dehydration dynamics of stilbite using synchrotron X-ray powder diffraction". American Mineralogist. 82 (7–8): 729–739. Bibcode:1997AmMin..82..729C. doi:10.2138/am-1997-7-810. S2CID 99122598.