Sulfuryl chloride fluoride

Sulfuryl chloride fluoride
Structure of sulfuryl chloride fluoride
Names
IUPAC name
Sulfuryl chloride fluoride
Other names
Sulfuryl fluoride chloride, TL-212
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.033.737 Edit this at Wikidata
EC Number
  • 237-126-2
1993
RTECS number
  • WT4900000
UNII
  • InChI=1S/ClFO2S/c1-5(2,3)4 checkY
    Key: IXPAAHZTOUOJJM-UHFFFAOYSA-N checkY
  • InChI=1/ClFO2S/c1-5(2,3)4
    Key: IXPAAHZTOUOJJM-UHFFFAOYAK
  • ClS(F)(=O)=O
Properties
ClFO2S
Molar mass 118.52 g/mol
Appearance colourless gas
Density 1.623 g/cm3 at 0 °C
Melting point −124.7 °C (−192.5 °F; 148.5 K)
Boiling point 7.1 °C (44.8 °F; 280.2 K)
hydrolyses
Solubility in other solvents SO2 and ether
Structure
tetrahedral
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
moderately toxic, corrosive
GHS labelling:
GHS05: CorrosiveGHS06: Toxic
Danger
H301, H311, H314, H331
P260, P261, P264, P270, P271, P280, P301+P310, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P310, P311, P312, P321, P322, P330, P361, P363, P403+P233, P405, P501
Safety data sheet (SDS) "External MSDS"
Related compounds
Related compounds
SO2Cl2,
SO2F2
ClSO2(NCO)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Sulfuryl chloride fluoride is a chemical compound with the formula SO2ClF. It is a colorless, easily condensed gas. It is a tetrahedral molecule.

Liquified sulfuryl chloride fluoride is employed as a solvent for highly oxidizing compounds.[1]

  1. ^ Koppe, Karsten; Bilir, Vural; Frohn, Hermann-J.; Mercier, Hélène P. A.; Schrobilgen, Gary J. (2007). "Syntheses, Solution Multi-NMR Characterization, and Reactivities of [C6F5Xe]+Salts of Weakly Coordinating Borate Anions, [BY4]-(Y = CF3, C6F5, CN, or OTeF5)". Inorganic Chemistry. 46 (22): 9425–9437. doi:10.1021/ic7010138. PMID 17902647.