Tetracalcium phosphate

Tetracalcium phosphate
Names
IUPAC name
Tetracalcium oxide diphosphate
Other names
Tetracalcium diphosphorus nonaoxide, tetracalcium oxygen(2-) diphosphate, calcium oxide phosphate, TTCP, TetCP, Thomas phosphate
Identifiers
3D model (JSmol)
ECHA InfoCard 100.013.767 Edit this at Wikidata
EC Number
  • 215-143-6
UNII
  • InChI=1S/4Ca.2H3O4P.O/c;;;;2*1-5(2,3)4;/h;;;;2*(H3,1,2,3,4);/q4*+2;;;-2/p-6
    Key: GBNXLQPMFAUCOI-UHFFFAOYSA-H
  • [O-2].[O-]P(=O)([O-])[O-].[O-]P(=O)([O-])[O-].[Ca+2].[Ca+2].[Ca+2].[Ca+2]
Properties
Ca4(PO4)2O
Molar mass 366.254124 g/mol
Appearance white
Melting point decomp
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Tetracalcium phosphate is the compound Ca4(PO4)2O, (4CaO·P2O5). It is the most basic of the calcium phosphates, and has a Ca/P ratio of 2, making it the most phosphorus poor phosphate.[1] It is found as the mineral hilgenstockite, which is formed in industrial phosphate rich slag (called "Thomas slag"). This slag was used as a fertiliser due to the higher solubility of tetracalcium phosphate relative to apatite minerals.[2] Tetracalcium phosphate is a component in some calcium phosphate cements that have medical applications.[1]

  1. ^ a b Moseke, C.; Gbureck, U. (October 2010). "Tetracalcium phosphate: Synthesis, properties and biomedical applications". Acta Biomaterialia. 6 (10): 3815–3823. doi:10.1016/j.actbio.2010.04.020. PMID 20438869.  – via ScienceDirect (Subscription may be required or content may be available in libraries.)
  2. ^ Walter E. Brown; Earl F. Epstein (November–December 1965). "Crystallography of Tetracalcium Phosphate". Journal of Research of the National Bureau of Standards Section A. 69A (6): 547–551. doi:10.6028/jres.069a.059. PMC 6599098. PMID 31927823.