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A thermoset polymer matrix is a synthetic polymer reinforcement where polymers act as binder or matrix to secure in place incorporated particulates, fibres or other reinforcements. They were first developed for structural applications,[1] such as glass-reinforced plastic radar domes on aircraft and graphite-epoxy payload bay doors on the Space Shuttle.
They were first used after World War II, and continuing research has led to an increased range of thermoset resins, polymers or plastics,[2] as well as engineering grade thermoplastics.[3] They were all developed for use in the manufacture of polymer composites with enhanced and longer-term service capabilities. Thermoset polymer matrix technologies also find use in a wide diversity of non-structural industrial applications.[4]
The foremost types of thermosetting polymers used in structural composites are benzoxazine resins, bis-maleimide resins (BMI), cyanate ester resins, epoxy (epoxide) resins, phenolic (PF) resins, unsaturated polyester (UP) resins, polyimides, polyurethane (PUR) resins, silicones, and vinyl esters.
- ^ Polymer Matrix Composites: Materials Usage, Design, and Analysis, SAE International, 2012, ISBN 978-0-7680-7813-8
- ^ Handbook of Thermoset Plastics, ed. S.H. Goodman, H. Dodiuk-Kenig, William Andrew Inc., USA, 3rd edition, 2013, ISBN 978-1-4557-3107-7
- ^ Handbook of Thermoplastics, ed. O. Olabisi, K Adewale, CRC Press, USA, 2nd edition, 2015, ISBN 978-1-466577220
- ^ Industrial Polymer Applications: Essential Chemistry and Technology, Royal Society of Chemistry, UK, 1st edition, 2016, ISBN 978-1782628149