Thiazyl trifluoride

Thiazyl trifluoride
Names
	IUPAC name Thiazyl trifluoride
	Other names Sulfur(VI) nitride trifluoride; Trifluorosulfanenitrile
Identifiers
CAS Number	15930-75-3 ;
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:30507 ;
ChemSpider	123471 ;
PubChem CID	140008;
CompTox Dashboard (EPA)	DTXSID30166628 ;
	InChI InChI=1S/F3NS/c1-5(2,3)4 Key: UQUPGRNSXINWBS-UHFFFAOYSA-N ; InChI=1/F3NS/c1-5(2,3)4 Key: UQUPGRNSXINWBS-UHFFFAOYAR;
	SMILES FS(F)(F)#N;
Properties
Chemical formula	NSF3
Molar mass	103.06 g·mol−1
Appearance	Colourless gas
Melting point	−72.6 °C (−98.7 °F; 200.6 K)
Boiling point	−27.1 °C (−16.8 °F; 246.1 K)
Structure
Molecular shape	Tetrahedral at the S atom
Hybridisation	sp3
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Thiazyl trifluoride is a chemical compound of nitrogen, sulfur, and fluorine, having the formula NSF₃. It exists as a stable, colourless gas, and is an important precursor to other sulfur-nitrogen-fluorine compounds.^[2] It has tetrahedral molecular geometry around the sulfur atom, and is regarded to be a prime example of a compound that has a sulfur-nitrogen triple bond.^[3]

^ Li, Bing-Yu; Su, Kexin; Van Meervelt, Luc; Verhelst, Steven H. L.; Ismalaj, Ermal; De Borggraeve, Wim M.; Demaerel, Joachim (2023-07-17). "Ex situ Generation of Thiazyl Trifluoride (NSF 3 ) as a Gaseous SuFEx Hub**" (PDF). Angewandte Chemie International Edition. 62 (29). doi:10.1002/anie.202305093. ISSN 1433-7851.
^ Oskar Glemser and Rüdiger Mews (1980). "Chemistry of Thiazyl Fluoride (NSF) and Thiazyl Trifluoride (NSF₃): A Quarter Century of Sulfur-Nitrogen-Fluorine Chemistry". Angew. Chem. Int. Ed. Engl. 19 (11): 883–899. doi:10.1002/anie.198008831.
^ Borrmann, T.; Lork, E.; Mews, R. D.; Parsons, S.; Petersen, J.; Stohrer, W. D.; Watson, P. G. (2008). "The crystal structures of NSF
₃ and (NSF₂N(CH₃)CH₂–)₂: How short is the 'Crystallographic' N≡S triple bond?". Inorganica Chimica Acta. 361 (2): 479–486. doi:10.1016/j.ica.2007.05.016.

[1] Li, Bing-Yu; Su, Kexin; Van Meervelt, Luc; Verhelst, Steven H. L.; Ismalaj, Ermal; De Borggraeve, Wim M.; Demaerel, Joachim (2023-07-17). "Ex situ Generation of Thiazyl Trifluoride (NSF 3 ) as a Gaseous SuFEx Hub**" (PDF). Angewandte Chemie International Edition. 62 (29). doi:10.1002/anie.202305093. ISSN 1433-7851.

[2] Oskar Glemser and Rüdiger Mews (1980). "Chemistry of Thiazyl Fluoride (NSF) and Thiazyl Trifluoride (NSF₃): A Quarter Century of Sulfur-Nitrogen-Fluorine Chemistry". Angew. Chem. Int. Ed. Engl. 19 (11): 883–899. doi:10.1002/anie.198008831.

[3] Borrmann, T.; Lork, E.; Mews, R. D.; Parsons, S.; Petersen, J.; Stohrer, W. D.; Watson, P. G. (2008). "The crystal structures of NSF
₃ and (NSF₂N(CH₃)CH₂–)₂: How short is the 'Crystallographic' N≡S triple bond?". Inorganica Chimica Acta. 361 (2): 479–486. doi:10.1016/j.ica.2007.05.016.

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