Thiophosphoryl bromide

Thiophosphoryl bromide
Names
Other names
Thiophosphoryl tribromide
Phosphorus thiobromide
Phosphorothioic tribromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.021.367 Edit this at Wikidata
EC Number
  • 223-502-3
  • InChI=1S/Br3PS/c1-4(2,3)5
    Key: OWNZHTHZRZVKSQ-UHFFFAOYSA-N
  • S=P(Br)(Br)Br
Properties
PSBr3
Molar mass 302.75 g·mol−1
Appearance yellow crystals[1][2]
Density 2.85 g cm−3[2]
Melting point 37.8 °C (100.0 °F; 310.9 K)
Boiling point 212 °C (414 °F; 485 K) decomposes[2]
Structure[3]
Cubic
Pa3, No. 205
a = 11.03 Å, b = 11.03 Å, c = 11.03 Å
Tetrahedral at the P atom
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Thiophosphoryl bromide is an inorganic compound with the formula PSBr3.[1]

  1. ^ a b Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 501–503. ISBN 978-0-08-037941-8.
  2. ^ a b c William M. Haynes, ed. (2016). CRC Handbook of Chemistry and Physics (97th ed.). CRC Press. p. 4-78. ISBN 978-1498754293.
  3. ^ "ICSD Entry: 39130". Cambridge Structural Database: Access Structures. Cambridge Crystallographic Data Centre. Retrieved 2022-10-30.