Thulium(III) chloride

Thulium(III) chloride
Names
	IUPAC name Thulium(III) chloride
	Other names Thulium chloride, thulium trichloride
Identifiers
CAS Number	13537-18-3 ;
3D model (JSmol)	Interactive image;
ECHA InfoCard	100.033.535
EC Number	236-904-9;
PubChem CID	61643;
RTECS number	XP0525000;
UNII	73TYF012WF ;
CompTox Dashboard (EPA)	DTXSID4065529 ;
	InChI InChI=1S/3ClH.Tm/h3*1H;/q;;;+3/p-3;
	SMILES Cl[Tm](Cl)Cl;
Properties
Chemical formula	TmCl3
Molar mass	275.292 g/mol
Appearance	yellow crystals
Density	3.98 g/cm3
Melting point	824 °C (1,515 °F; 1,097 K)
Boiling point	1,490 °C (2,710 °F; 1,760 K)
Solubility in water	heptahydrate: very soluble
Solubility	heptahydrate: very soluble in ethanol
Structure
Crystal structure	Monoclinic, mS16
Space group	C12/m1, No. 12
Coordination geometry	6
Thermochemistry
Std enthalpy of; formation (ΔfH⦵298)	-966.6 kJ/mol
Hazards
	Occupational safety and health (OHS/OSH):
Main hazards	Irritant
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H315, H319, H335
Precautionary statements	P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P332+P313, P337+P313, P362, P403+P233, P405, P501
Related compounds
Other anions	Thulium(III) oxide
Other cations	Erbium(III) chloride; Ytterbium(III) chloride; Thulium(II) chloride
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Thulium(III) chloride or thulium trichloride is as an inorganic salt composed of thulium and chlorine with the formula TmCl₃. It forms yellow crystals. Thulium(III) chloride has the YCl₃ (AlCl₃) layer structure with octahedral thulium ions.^[5] It has been used as a starting material for some exotic nanostructures prepared for NIR photocatalysis.^[6]^[7]

^ Cite error: The named reference rare was invoked but never defined (see the help page).
^ "Chemistry: Periodic Table: Thulium: compound data (thulium (III) chloride)". WebElements. Archived from the original on 2008-12-01. Retrieved 2008-06-27.
^ Perry, Dale L.; Phillips, Sidney L. (1995). Handbook of Inorganic Compounds. CRC Press. p. 512. ISBN 0-8493-8671-3. Retrieved 2008-06-27.
^ "Thulium trichloride". pubchem.ncbi.nlm.nih.gov.
^ Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford Science Publications ISBN 0-19-855370-6
^ Cite error: The named reference SigmaH was invoked but never defined (see the help page).
^ Bai, Lijie; Jiang, Wenya; Gao, Chunxiao; Zhong, Shuxian; Zhao, Leihong; Li, Zhengquan; Bai, Song (2016-11-17). "Facet engineered interface design of NaYF4:Yb,Tm upconversion nanocrystals on BiOCl nanoplates for enhanced near-infrared photocatalysis". Nanoscale. 8 (45): 19014–19024. doi:10.1039/C6NR05720A. ISSN 2040-3372. PMID 27808315.

[rare-1] Cite error: The named reference rare was invoked but never defined (see the help page).

[web-2] "Chemistry: Periodic Table: Thulium: compound data (thulium (III) chloride)". WebElements. Archived from the original on 2008-12-01. Retrieved 2008-06-27.

[handin-3] Perry, Dale L.; Phillips, Sidney L. (1995). Handbook of Inorganic Compounds. CRC Press. p. 512. ISBN 0-8493-8671-3. Retrieved 2008-06-27.

[4] "Thulium trichloride". pubchem.ncbi.nlm.nih.gov.

[5] Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford Science Publications ISBN 0-19-855370-6

[SigmaH-6] Cite error: The named reference SigmaH was invoked but never defined (see the help page).

[7] Bai, Lijie; Jiang, Wenya; Gao, Chunxiao; Zhong, Shuxian; Zhao, Leihong; Li, Zhengquan; Bai, Song (2016-11-17). "Facet engineered interface design of NaYF4:Yb,Tm upconversion nanocrystals on BiOCl nanoplates for enhanced near-infrared photocatalysis". Nanoscale. 8 (45): 19014–19024. doi:10.1039/C6NR05720A. ISSN 2040-3372. PMID 27808315.

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