Tobermorite

Tobermorite
Crystalline mass of tobermorite
General
CategorySilicate mineral,
Calcium silicate hydrate
Formula
(repeating unit)
Ca5Si6O16(OH)2·4H2O, or;
Ca5Si6(O,OH)18·5H2O
IMA symbolTbm[1]
Strunz classification9.DG.10
Crystal systemOrthorhombic
Crystal classDisphenoidal (222)
H-M symbol: (2 2 2)
Space groupC2221 (no. 20)
Unit cella = 11.17 Å, b = 7.38 Å
c = 22.94 Å; β = 90°; Z = 4
Identification
Formula mass702.36 g/mol
ColorPale pinkish white, white, brown
Crystal habitAs minute laths; fibrous bundles, rosettes or sheaves, radiating or plumose, fine granular, massive.
Cleavage{001} Perfect, {100} Imperfect
Mohs scale hardness2.5
LusterVitreous, silky in fibrous aggregates
StreakWhite
DiaphaneityTranslucent to translucent
Specific gravity2.423 – 2.458
Optical propertiesBiaxial (+)
Refractive indexnα = 1.570 nβ = 1.571 nγ = 1.575
Birefringenceδ = 0.005
Ultraviolet fluorescenceFluorescent, Short UV:weak white to yellow, Long UV:weak white to yellow
References[2][3][4]

Tobermorite is a calcium silicate hydrate mineral with chemical formula: Ca5Si6O16(OH)2·4H2O or Ca5Si6(O,OH)18·5H2O.

Two structural varieties are distinguished: tobermorite-11 Å and tobermorite-14 Å. Tobermorite occurs in hydrated cement paste and can be found in nature as an alteration mineral in metamorphosed limestone and in skarn. It has been reported to occur in the Maqarin Area of north Jordan and in the Crestmore Quarry near Crestmore Heights, Riverside County, California.

Tobermorite was first described in 1880 for an occurrence in Scotland, on the Isle of Mull, around the locality of Tobermory.[3][5]

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (2005). "Tobermorite" (PDF). Handbook of Mineralogy. Mineral Data Publishing. Retrieved 27 July 2022.
  3. ^ a b Mineralogy Database, Mindat.org, retrieved 27 July 2022
  4. ^ Barthelmy, David (2014). "Lavendulan Mineral Data". Webmineral.com. Retrieved 27 July 2022.
  5. ^ Scottish physician and amateur mineralogist Matthew Forster Heddle (1828–1897) first described tobermorite in: Heddle (1880). "Preliminary notice of substances which may prove to be new minerals. Part second". Mineralogical Magazine and Journal of the Mineralogical Society. 4: 117–123. doi:10.1180/minmag.1880.004.18.04. See pp. 119–121.