Trimethyl borate

Trimethyl borate
Names
IUPAC name
Trimethyl borate
Other names
Trimethoxyborane
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.004.063 Edit this at Wikidata
EC Number
  • 204-468-9
UNII
  • InChI=1S/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3 checkY
    Key: WRECIMRULFAWHA-UHFFFAOYSA-N checkY
  • InChI=1/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3
    Key: WRECIMRULFAWHA-UHFFFAOYAY
  • O(B(OC)OC)C
Properties
C3H9BO3
Molar mass 103.91 g·mol−1
Appearance colourless liquid
Density 0.932 g/ml
Melting point −34 °C (−29 °F; 239 K)
Boiling point 68 to 69 °C (154 to 156 °F; 341 to 342 K)
decomposition
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
 flammable
Related compounds
Other cations
 Trimethyl phosphite
Tetramethyl orthosilicate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Trimethyl borate is the organoboron compound with the formula B(OCH3)3 and a metal alkoxide. It is a colourless liquid that burns with a green flame.[1] It is an intermediate in the preparation of sodium borohydride and is a popular reagent in organic chemistry. It is a weak Lewis acid (AN = 23, Gutmann-Beckett method).[2]

This chemical is quite flammable and burns with a green flame

Borate esters are prepared by heating boric acid or related boron oxides with alcohols under conditions where water is removed by azeotropic distillation. [1]

  1. ^ a b Robert J. Brotherton; C. Joseph Weber; Clarence R. Guibert; John L. Little (2000). "Boron Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. ISBN 978-3527306732.
  2. ^ M.A. Beckett, G.C. Strickland, J.R. Holland, and K.S. Varma, "A convenient NMR method for the measurement of Lewis acidity at boron centres: correlation of reaction rates of Lewis acid initiated epoxide polymerizations with Lewis acidity", Polymer, 1996, 37, 4629–4631. doi: 10.1016/0032-3861(96)00323-0