Warikahnite

Warikahnite
Warikahnite, Tsumeb mine, Namibia, 0.6 × 0.4 × 0.1 cm
General
CategoryArsenate minerals
Formula
(repeating unit)
Zn3(AsO4)2·2H2O
IMA symbolWar[1]
Strunz classification8.CA.35
Crystal systemTriclinic
Crystal classPinacoidal (1)
(same H-M symbol)
Space groupP1
Unit cella = 6.71 Å, b = 8.98 Å
c = 14.53 Å; α = 105.59°
β = 93.44°, γ = 108.68°; Z = 4
Identification
Formula mass510.04 g/mol
ColorPale yellow to colorless; honey-yellow; orange
Crystal habitAcicular; radial
Cleavage[001] perfect, [010] good, [100] good
FractureBrittle
Mohs scale hardness2
LusterVitreous, waxy
StreakWhite
DiaphaneityTransparent
Specific gravity4.28
Optical propertiesBiaxial (+)
Refractive indexnα = 1.747 nβ = 1.753 nγ = 1.768
Birefringenceδ = 0.021
2V angle75° measured
References[2][3][4][5]

Warikahnite is a rare zinc arsenate mineral of the triclinic crystal system with Hermann-Mauguin notation 1, belonging to the space group P1.[6] It occurs in the Tsumeb mine in Namibia on corroded tennantite in the second oxidation zone under hydrothermal conditions in a dolomite-hosted polymetallic ore deposit.[5][7] It is associated with adamite, stranskiite, koritnigite, claudetite, tsumcorite, and ludlockite. The origin of discovery was in a dolomite ore formation within an oxidized hydrothermal zone, in the E9 pillar, 31st level of the Tsumeb Mine in Namibia, Southwest Africa.[2][5] It has also been found at Lavrion, Greece and Plaka, Greece as microscopic white needles.[6]

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b http://rruff.geo.arizona.edu/doclib/hom/warikahnite.pdf Mineral Handbook
  3. ^ http://webmineral.com/data/Warikahnite.shtml Webmineral
  4. ^ http://www.mindat.org/min-4244.html Mindat
  5. ^ a b c Fleischer, Michael; L. J. Cabri; A. Pabst (1980). "New mineral names" (PDF). American Mineralogist. 65: 406–408. Retrieved 2010-01-03.
  6. ^ a b Pinch, William W. (July 2005). "Warikahnite: some background on the cover specimen". The Mineralogical Record. 36 (4). The Mineralogical, Inc.: 315(1).
  7. ^ Anthony, J. W., Bideaux, R. A., Bladh, K. W., and Nichols, M. C. (2000) Handbook of Mineralogy. Volume IV: Arsenates, Phosphates and Vanadates. Mineral Data Publishing Company, Tucson, Arizona, p. 644