Zone melting

(left) Pfann, at left, showing the first zone refining tube, Bell Labs, 1953
(right) Vertical zone refining, 1961. The induction heating coil melts a section of the metal bar in the tube. The coil moves slowly down the tube, moving the molten zone to the end of the bar.
Crystallization
Fundamentals
Concepts
Methods and technology

Zone melting (or zone refining, or floating-zone method, or floating-zone technique) is a group of similar methods of purifying crystals, in which a narrow region of a crystal is melted, and this molten zone is moved along the crystal. The molten region melts impure solid at its forward edge and leaves a wake of purer material solidified behind it as it moves through the ingot. The impurities concentrate in the melt, and are moved to one end of the ingot. Zone refining was invented by John Desmond Bernal[1] and further developed by William G. Pfann[2] in Bell Labs as a method to prepare high-purity materials, mainly semiconductors, for manufacturing transistors. Its first commercial use was in germanium, refined to one atom of impurity per ten billion,[3] but the process can be extended to virtually any solutesolvent system having an appreciable concentration difference between solid and liquid phases at equilibrium.[4] This process is also known as the float zone process, particularly in semiconductor materials processing.

A diagram of the vertical zone refining process used to grow single-crystal ice from an initially polycrystalline material. The convection in the melt is a result of water's density maximum at 4 °C.
Silicon crystal in the beginning of the growth process
Growing silicon crystal
A high-purity (5N) tantalum single crystal, made by the floating-zone process (cylindrical object in the center)
  1. ^ Brown, Andrew (2005-11-24). J. D. Bernal: The Sage of Science. OUP Oxford. ISBN 9780198515449.
  2. ^ William G. Pfann (1966) Zone Melting, 2nd edition, John Wiley & Sons
  3. ^ ”Zone melting”, entry in The World Book Encyclopedia, Volume 21, W-X-Y-Z, 1973, page 501.
  4. ^ Float Zone Crystal Growth